Journal Press India®
Review of Synthesis, Characterization, Mechanical and Electrical Properties of CNTs/PANI Nanocomposite
Vol 5 , Issue 4 , October - December 2017 | Pages: 47-54 | Research Paper
Received: January 25, 2017 | Revised: February 20, 2017 | Accepted: February 28, 2017 | Published Online: March 15, 2017
Author Details
( * ) denotes Corresponding author
1.
Md Zakir Hussain, Department of Mechanical Engineering, Jamia Millia Islamia, New Delhi, Delhi, India
2.
* Sabah Khan, Department of Mechanical Engineering, Jamia Millia Islamia, New Delhi, Delhi, India (khansabah629@gmail.com)
3.
Suborna Haque, Department of English, Goalpara Polytechnic, Goalpara, Assam, India
4.
Bhaskarjyoti Pathak, Department of English, Goalpara Polytechnic, Goalpara, Assam, India
In recent years, attention has been made by researchers to fabricate carbon nano-tubes/Polyaniline (CNTs/PANI) nanocomposites due to its simple method of preparation, low cost, environmental friendly, excellent capacitive performance. The discovery of carbon nanotubes with unique electrical, thermal and mechanical properties has attracted researchers used as a filler material for applications in engineering discipline. This review gives a broad study on ongoing research effort on synthesis, characterization, mechanical and electrical properties of CNTs/PANI nanocomposites.
Keywords
Carbon Nano Tubes (CNTs); Polyaniline (PANI); XRD; FESEM; Young’s Modulus; Electrical Conductivity.
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Ratner MA, Shriver DF. Ion transport in solvent-free polymers. Chemical Reviews. 1988 Jan;88(1):109-24.
Eisazadeh H, Spinks G, Wallace GG. Conductive electroactive plant containing polypyrrole colloids. InMaterials forum 1994 (Vol. 17, No. 3, pp. 241-245). Institute of Metals and Materials Australasia.
Falcão EH, de Azevêdo WM. Polyaniline-poly (vinyl alcohol) composite as an optical recording material. Synthetic Metals. 2002 Apr 30;128(2):149-54.
Misoska V, Ding J, Davey JM, Price WE, Ralph SF, Wallace GG. Polypyrrole membranes containing chelating ligands: synthesis, characterisation and transport studies. Polymer. 2001 Oct 31;42(21):8571-9.
Benabderrahmane S, Bousalem S, Mangeney C, Azioune A, Vaulay MJ, Chehimi MM. Interfacial physicochemical properties of functionalized conducting polypyrrole particles. Polymer. 2005 Feb 7;46(4):1339-46.
Saboktakin MR, Maharramov A, Ramazanov MA. Synthesis and characterization of Polyaniline / Poly (p-hydroxyaniline) / Fe3O4 magnetic nanocomposite. Journal of Non-Oxide Glasses. 2009 Sep;1 (3): 211-5.].
Tjong SC. Carbon nanotube reinforced composites: metal and ceramic matrices. John Wiley & Sons; 2009 Apr 8.
A. R. Subrahmanyama, V. Geethaa, Atul kumarb, A. Alakanandanac, J. Siva Kumard. Mechanical and Electrical Conductivity Studies of PANI-PVA and PANI-PEO Blends. IJMS Vol.2 Iss.1 2012 PP.27-30
Helena Valentová H, Prokeš J, Nedbal J, Stejskal J. Effect of compression pressure on mechanical and electrical properties of polyaniline pellets. Chemical Papers 67 (8) 1109–1112 (2013)
S. Ghatak,G. Chakraborty, A. K. Meikap,T. Woods,R. Babu,W. J. Blau. Synthesis and characterization of polyaniline/carbon nanotube composites.Journal Applied Polymer Science. Volume 119, Issue 215 January 2011, Pages 1016–1025
Shumaila Akram, Samina Husain, and Mushahid Husain.Field-emission properties of carbon nanotube-polyaniline composites. Society for plastics Engineers, Plastics research online, DOI: 10.2417/spepro.005004
Mahore RP, Kondawar SB, Burghate DK, Meshram BH. Electrochemical performance of polyaniline / CNT / MnO2 and polypyrrole / CNT / MnO2 ternary nanocomposites as electrode materials for supercapacitor. Journal of the Chinese Advanced Materials Society. 2015; 3(1):45-56.
Bachhav SG, Patil DR. Synthesis and characterization of polyaniline-multiwalled carbon nanotube nanocomposites and its electrical percolation behavior. American Journal of Materials Science. 2015;5(4):90-5.
Zhang Z, Zhang F, Jiang X, Liu Y, Guo Z, Leng J. Electrospinning and microwave absorption of polyaniline/polyacrylonitrile/multiwalled carbon nanotubes nanocomposite fibers. Fibers and Polymers. 2014 Nov 1;15(11):2290-6.
Modak P, Kondawar SB, Nandanwar DV. Synthesis and characterization of conducting polyaniline/graphene nanocomposites for electromagnetic interference shielding. Procedia Materials Science. 2015 Jan 1;10:588-94.
Lee BW, Park CH, Song JH, Kim YJ. Controlling the Shapes and Electrical Conductivities of Polyaniline-Wrapped MWCNTs. Journal of nanoscience and nanotechnology. 2011 Jul 1;11(7):6089-94.
Shin K, Al-Mashat L, Song JS, Han SH, Ahn DS, Yoo BY, Kalantar-Zadeh K, Wlodarski W. Polyaniline/MWCNT nanocomposite based hydrogen sensor operating at room temperature. Sensor Letters. 2011 Feb 1;9(1):69-72.
Kim JW, Siochi EJ, Carpena-Núñez J, Wise KE, Connell JW, Lin Y, Wincheski RA. Polyaniline / carbon nanotube sheet nano-composites: fabrication and characterization. ACS applied materials & interfaces. 2013 Aug 28;5(17):8597-606.
Gupta TK, Singh BP, Mathur RB, Dhakate SR. Multi-walled carbon nanotube–graphene–polyaniline multiphase nano-composite with superior electro-magnetic shielding effectiveness. Nano-scale. 2014; 6(2):842-51.
Goswami M, Mukherjee A, Ghosh R, Basu S, Meikap AK. Enhanced magnetoconductivity and electrical property of MWCNT-CdS nanocomposite embedded in polyaniline. Solid State Sciences. 2016 Oct 31;60:37-44.
Saini P, Choudhary V, Singh BP, Mathur RB, Dhawan SK. Polyaniline–MWCNT nanocomposites for microwave absorption and EMI shielding. Materials Chemistry and Physics. 2009 Feb 15;113(2):919-26.
Karim MR, Islam A, Akhtaruzzaman MD, Han L, Al-Ahmari A. Multiwall carbon nanotube coated with conducting polyaniline nanocomposites for quasi-solid-state dye-sensitized solar cells. Journal of Chemistry. 2012 Nov 19;2013.
Kar P, Choudhury A. Carboxylic acid functionalized multi-walled carbon nanotube doped polyaniline for chloroform sensors. Sensors and actuators B: Chemical. 2013 Jul 5;183:25-33.
Cheng Q, Tang J, Shinya N, Qin LC. Polyaniline modified graphene and carbon nanotube composite electrode for asymmetric supercapacitors of high energy density. Journal of Power Sources. 2013 Nov 1;241:423-8.
Cabezas AL, Liu X, Chen Q, Zhang SL, Zheng LR, Zhang ZB. Influence of Carbon Nanotubes on Thermal Stability of Water-Dispersible Nanofibrillar Polyaniline/Nanotube Composite. Materials. 2012 Feb 17;5(2):327-35.
Blighe FM, Diamond D, Coleman JN, Lahiff E. Increased response/recovery lifetimes and reinforcement of polyaniline nanofiber films using carbon nanotubes. Carbon. 2012 Apr 30;50(4):1447-54.
Nikzad L, Vaezi MR, Yazdani B. Synthesis of carbon nanotube–Poly aniline nano composite and evaluation of electrochemical properties. InInternational Journal of Modern Physics: Conference Series 2012 (Vol. 5, pp. 527-535). World Scientific Publishing Company.
Kondawar SB, Deshpande MD, Agrawal SP. Transport properties of conductive polyaniline nanocomposites based on carbon nanotubes. International Journal of Composite Materials. 2012;2(3):32-6.
Sabzi ER, Rezapour K, Samadi N. Polyaniline-multi-wall-carbon nanotube nanocomposites as a dopamine sensor. Journal of the Serbian Chemical Society. 2010;75(4):537-49.
Yang J, Wang X, Wang X, Jia R, Huang J. Preparation of highly conductive CNTs/polyaniline composites through plasma pretreating and in-situ polymerization. Journal of Physics and Chemistry of Solids. 2010 Apr 30;71(4):448-52.
Yao Q, Chen L, Zhang W, Liufu S, Chen X. Enhanced thermoelectric performance of single-walled carbon nanotubes/polyaniline hybrid nanocomposites. Acs Nano. 2010 Apr 1;4(4):2445-51.
Han J, Sohn J, Cho S, Jo Y, Kim J, Woo H, Kim H, Inamdar AI, Kim H, Im H. Synthesis of self-assembling carbon nanotube-polyaniline nanocomposite on a flexible graphene-coated substrate for electrochemical electrode applications. Journal of the Korean Physical Society. 2015;67(3):512-7.
Jeevananda T, Kim NH, Heo SB, Lee JH. Synthesis and characterization of polyaniline‐multiwalled carbon nanotube nanocomposites in the presence of sodium dodecyl sulfate. Polymers for Advanced Technologies. 2008;19(12):1754-62.
Razak SI, Ahmad AL, Zein SH. Polymerisation of protonic polyaniline/multi-walled carbon nanotubes-manganese dioxide nanocomposites. J. Phys. Sci. 2009; 20(1).
Ratner MA, Shriver DF. Ion transport in solvent-free polymers. Chemical Reviews. 1988 Jan;88(1):109-24.
Eisazadeh H, Spinks G, Wallace GG. Conductive electroactive plant containing polypyrrole colloids. InMaterials forum 1994 (Vol. 17, No. 3, pp. 241-245). Institute of Metals and Materials Australasia.
Falcão EH, de Azevêdo WM. Polyaniline-poly (vinyl alcohol) composite as an optical recording material. Synthetic Metals. 2002 Apr 30;128(2):149-54.
Misoska V, Ding J, Davey JM, Price WE, Ralph SF, Wallace GG. Polypyrrole membranes containing chelating ligands: synthesis, characterisation and transport studies. Polymer. 2001 Oct 31;42(21):8571-9.
Benabderrahmane S, Bousalem S, Mangeney C, Azioune A, Vaulay MJ, Chehimi MM. Interfacial physicochemical properties of functionalized conducting polypyrrole particles. Polymer. 2005 Feb 7;46(4):1339-46.
Saboktakin MR, Maharramov A, Ramazanov MA. Synthesis and characterization of Polyaniline / Poly (p-hydroxyaniline) / Fe3O4 magnetic nanocomposite. Journal of Non-Oxide Glasses. 2009 Sep;1 (3): 211-5.].
Tjong SC. Carbon nanotube reinforced composites: metal and ceramic matrices. John Wiley & Sons; 2009 Apr 8.
A. R. Subrahmanyama, V. Geethaa, Atul kumarb, A. Alakanandanac, J. Siva Kumard. Mechanical and Electrical Conductivity Studies of PANI-PVA and PANI-PEO Blends. IJMS Vol.2 Iss.1 2012 PP.27-30
Helena Valentová H, Prokeš J, Nedbal J, Stejskal J. Effect of compression pressure on mechanical and electrical properties of polyaniline pellets. Chemical Papers 67 (8) 1109–1112 (2013)
S. Ghatak,G. Chakraborty, A. K. Meikap,T. Woods,R. Babu,W. J. Blau. Synthesis and characterization of polyaniline/carbon nanotube composites.Journal Applied Polymer Science. Volume 119, Issue 215 January 2011, Pages 1016–1025
Shumaila Akram, Samina Husain, and Mushahid Husain.Field-emission properties of carbon nanotube-polyaniline composites. Society for plastics Engineers, Plastics research online, DOI: 10.2417/spepro.005004
Mahore RP, Kondawar SB, Burghate DK, Meshram BH. Electrochemical performance of polyaniline / CNT / MnO2 and polypyrrole / CNT / MnO2 ternary nanocomposites as electrode materials for supercapacitor. Journal of the Chinese Advanced Materials Society. 2015; 3(1):45-56.
Bachhav SG, Patil DR. Synthesis and characterization of polyaniline-multiwalled carbon nanotube nanocomposites and its electrical percolation behavior. American Journal of Materials Science. 2015;5(4):90-5.
Zhang Z, Zhang F, Jiang X, Liu Y, Guo Z, Leng J. Electrospinning and microwave absorption of polyaniline/polyacrylonitrile/multiwalled carbon nanotubes nanocomposite fibers. Fibers and Polymers. 2014 Nov 1;15(11):2290-6.
Modak P, Kondawar SB, Nandanwar DV. Synthesis and characterization of conducting polyaniline/graphene nanocomposites for electromagnetic interference shielding. Procedia Materials Science. 2015 Jan 1;10:588-94.
Lee BW, Park CH, Song JH, Kim YJ. Controlling the Shapes and Electrical Conductivities of Polyaniline-Wrapped MWCNTs. Journal of nanoscience and nanotechnology. 2011 Jul 1;11(7):6089-94.
Shin K, Al-Mashat L, Song JS, Han SH, Ahn DS, Yoo BY, Kalantar-Zadeh K, Wlodarski W. Polyaniline/MWCNT nanocomposite based hydrogen sensor operating at room temperature. Sensor Letters. 2011 Feb 1;9(1):69-72.
Kim JW, Siochi EJ, Carpena-Núñez J, Wise KE, Connell JW, Lin Y, Wincheski RA. Polyaniline / carbon nanotube sheet nano-composites: fabrication and characterization. ACS applied materials & interfaces. 2013 Aug 28;5(17):8597-606.
Gupta TK, Singh BP, Mathur RB, Dhakate SR. Multi-walled carbon nanotube–graphene–polyaniline multiphase nano-composite with superior electro-magnetic shielding effectiveness. Nano-scale. 2014; 6(2):842-51.
Goswami M, Mukherjee A, Ghosh R, Basu S, Meikap AK. Enhanced magnetoconductivity and electrical property of MWCNT-CdS nanocomposite embedded in polyaniline. Solid State Sciences. 2016 Oct 31;60:37-44.
Saini P, Choudhary V, Singh BP, Mathur RB, Dhawan SK. Polyaniline–MWCNT nanocomposites for microwave absorption and EMI shielding. Materials Chemistry and Physics. 2009 Feb 15;113(2):919-26.
Karim MR, Islam A, Akhtaruzzaman MD, Han L, Al-Ahmari A. Multiwall carbon nanotube coated with conducting polyaniline nanocomposites for quasi-solid-state dye-sensitized solar cells. Journal of Chemistry. 2012 Nov 19;2013.
Kar P, Choudhury A. Carboxylic acid functionalized multi-walled carbon nanotube doped polyaniline for chloroform sensors. Sensors and actuators B: Chemical. 2013 Jul 5;183:25-33.
Cheng Q, Tang J, Shinya N, Qin LC. Polyaniline modified graphene and carbon nanotube composite electrode for asymmetric supercapacitors of high energy density. Journal of Power Sources. 2013 Nov 1;241:423-8.
Cabezas AL, Liu X, Chen Q, Zhang SL, Zheng LR, Zhang ZB. Influence of Carbon Nanotubes on Thermal Stability of Water-Dispersible Nanofibrillar Polyaniline/Nanotube Composite. Materials. 2012 Feb 17;5(2):327-35.
Blighe FM, Diamond D, Coleman JN, Lahiff E. Increased response/recovery lifetimes and reinforcement of polyaniline nanofiber films using carbon nanotubes. Carbon. 2012 Apr 30;50(4):1447-54.
Nikzad L, Vaezi MR, Yazdani B. Synthesis of carbon nanotube–Poly aniline nano composite and evaluation of electrochemical properties. InInternational Journal of Modern Physics: Conference Series 2012 (Vol. 5, pp. 527-535). World Scientific Publishing Company.
Kondawar SB, Deshpande MD, Agrawal SP. Transport properties of conductive polyaniline nanocomposites based on carbon nanotubes. International Journal of Composite Materials. 2012;2(3):32-6.
Sabzi ER, Rezapour K, Samadi N. Polyaniline-multi-wall-carbon nanotube nanocomposites as a dopamine sensor. Journal of the Serbian Chemical Society. 2010;75(4):537-49.
Yang J, Wang X, Wang X, Jia R, Huang J. Preparation of highly conductive CNTs/polyaniline composites through plasma pretreating and in-situ polymerization. Journal of Physics and Chemistry of Solids. 2010 Apr 30;71(4):448-52.
Yao Q, Chen L, Zhang W, Liufu S, Chen X. Enhanced thermoelectric performance of single-walled carbon nanotubes/polyaniline hybrid nanocomposites. Acs Nano. 2010 Apr 1;4(4):2445-51.
Han J, Sohn J, Cho S, Jo Y, Kim J, Woo H, Kim H, Inamdar AI, Kim H, Im H. Synthesis of self-assembling carbon nanotube-polyaniline nanocomposite on a flexible graphene-coated substrate for electrochemical electrode applications. Journal of the Korean Physical Society. 2015;67(3):512-7.
Jeevananda T, Kim NH, Heo SB, Lee JH. Synthesis and characterization of polyaniline‐multiwalled carbon nanotube nanocomposites in the presence of sodium dodecyl sulfate. Polymers for Advanced Technologies. 2008;19(12):1754-62.
Razak SI, Ahmad AL, Zein SH. Polymerisation of protonic polyaniline/multi-walled carbon nanotubes-manganese dioxide nanocomposites. J. Phys. Sci. 2009; 20(1).
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